Reaction with sodium:
2R–OH + 2Na → 2R–ONa + H₂↑
(forms sodium alkoxide and hydrogen gas)
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Oxidation:
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Primary alcohols → aldehydes → carboxylic acids
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Secondary alcohols → ketones
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Tertiary alcohols → resistant to oxidation
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Dehydration:
R–CH₂CH₂–OH → R–CH=CH₂ + H₂O (with concentrated H₂SO₄) -
Esterification:
R–OH + R′–COOH → R′–COOR + H₂O (in presence of acid catalyst) -
Halogenation:
R–OH + HX → R–X + H₂O (forms alkyl halides)
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